Objectives of Work Package 13
To ascertain the appropriate circumstances in which
surface-applied corrosion inhibitors represent an optimal repair strategy.
This involves consideration of the inter-relation of inhibitor
depassivation mechanism, inhibitor migration, and the characteristics of
the deteriorated concrete, especially chloride content and permeability.
Proposed tasks
The work is divided into six tasks.
Task 13.1 Basic mechanism study will:
| determine the mechanisms of passivation due to the inhibitors,
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| assess the influence of corroded reinforcement state on corrosion
inhibitor concentration requirement, |
| underpin the interpretation of data generated in the applied
re-search of Task 13.2 (Chloride and inhibitor concentration) and
partly also that of Task 13.3 (Concrete permeability). |
Task 13.2 Chloride and inhibitor concentration will examine
the potential existence of an effectiveness envelope bounded by the
ratio of chloride to inhibitor concentration. The objective of Task 13.2
is to quantify the relationship between the chloride level and the
optimal inhibitor concentration so that one can ex-press (in terms of
the probability) the likelihood of effective corrosion control through
inhibitor application in a particular case.
Task 13.3 Concrete permeability will examine the potential
existence of an effectiveness envelope bounded by concrete permeability
values. The objectives of this task 13.3 are to:
| quantify the rate of penetration of specific inhibitors into
concretes representing a range of permeabilities and to |
| investigate the relationship of permeability testing to degree of
penetration. |
Task 13.4 Influence on mechanical properties will examine
whether or not the inhibitors have any significant influence on the
mechanical properties of mature concrete. The objective of this task is
to determine the relative influence, if any, of amino alcohol and sodium
monofluorophosphate inhibitors on the following properties of mature
concrete:
| freeze/thaw resistance, |
| compressive strength, |
| tensile strength, |
| flexural strength, |
| permeability, |
| shrinkage and |
| reinforcement bond. |
Task 13.5 Field trials will involve two distinct aspects. The
first, and most important, will be the monitoring of bridges
rehabilitated through application of amino alcohol inhibitors. The
second aspect will involve limited field exposure trials using specimens
cast in the laboratory and identical to some of those used in Task 13.2.
The objectives of this task are to:
| determine significant factors of influence observable through
field experience, |
| validate trends observed in laboratory trials by comparison with
experience in both field trials on rehabilitated structures and
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| control specimens exposed to a marine environment.
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Task 13.6 Specifications Description will bring together the
findings of WP 13 in a manner suitable for input to WP 12. The
objectives of Task 13.6 are to:
| identify specification issues in the selection of corrosion
inhibitors as an acceptable rehabilitation solution on a particular
structure through a review of final reports on laboratory and field
trials, |
| prepare guidelines on the use of inhibitors in highway structure
maintenance, |
| input findings of Work Package WP13 to Work Package WP12.
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